Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions

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Фізико-технічні та математичні науки
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Відділення фізико-технічних проблем матеріалознавства
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Functional Materials
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Functional Materials, 2017, том 24
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Functional Materials, 2017, № 2
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dc.contributor.author	Zatovsky, I.V.
dc.contributor.author	Slobodyanik, N.S.
dc.contributor.author	Ushchapivska, T.I.
dc.contributor.author	Han, W.
dc.date.accessioned	2018-06-16T15:38:10Z
dc.date.available	2018-06-16T15:38:10Z
dc.date.issued	2017
dc.identifier.citation	Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ.	uk_UA
dc.identifier.issn	1027-5495
dc.identifier.other	DOI: https://doi.org/10.15407/fm24.02.298
dc.identifier.uri	http://dspace.nbuv.gov.ua/handle/123456789/136747
dc.description.abstract	This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %.	uk_UA
dc.language.iso	en	uk_UA
dc.publisher	НТК «Інститут монокристалів» НАН України	uk_UA
dc.relation.ispartof	Functional Materials
dc.subject	Technology	uk_UA
dc.title	Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions	uk_UA
dc.type	Article	uk_UA
dc.status	published earlier	uk_UA