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періодичних видань НАН України
періодичних видань НАН України
Molecular probing of low-temperature incommensurate phases
Репозиторій DSpace/Manakin
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Molecular probing of low-temperature incommensurate phases
Тема:
Biological Systems at Low Temperatures
Інший ID:
PACS: 61.44.Fw, 62.50.+p, 64.70.Rh, 78.55.Kz
Посилання:
Molecular probing of low-temperature incommensurate phases / J. Kikas, A. Suisalu, A. Laisaar, An. Kuznetsov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1057-1060. — Бібліогр.: 13 назв. — англ.
Підтримка:
Earlier collaboration with J. Friedrich and his group has initiated these studies. Support from the Estonian Science Foundation under grants No. 5544 and 3873 is greatly appreciated.
Дата:
2003
Переглядів:
686
Завантажень:
421
Анотація:
Two-dimensional (2D) excitation-emission spectra of biphenyl doped with free-base chlorin were measured at 5 K under various pressures up to 350 MPa. Besides the features related to zero-phonon lines and their phonon sidebands, a broad spectral band amounting to 80% of the total intensity at 5 K was revealed in the 2D spectra. The obtained inhomogeneous distribution function shows drastic changes with increasing pressure — the triplet structure observable at normal pressure in the incommensurate phase ICIII of biphenyl converges to a singlet in the high-pressure commensurate phase CI. These observations are assumed to reflect specific for incommensurate phases relaxation after an optical excitation of probe molecules and interaction of them with the incommensurate modulation wave.
