Анотація:
We briefly review aspects of superconductive persistent currents in Josephson junctions of the
S/I/S, S/O/S and S/N/S types, focusing on the origin of jumps in the current versus phase
dependences, and discuss in more detail the persistent as well as «spontaneous» currents in the
Aharonov–Bohm mesoscopic and nanoscopic (macromolecular) structures. A fixed-number-of-electrons
mesoscopic or macromolecular conducting ring is shown to be unstable against structural
transformation removing spatial symmetry (in particular, azimuthal periodicity) of its electron-
lattice Hamiltonian. In case when the transformation is blocked by strong coupling to an external
azimuthally symmetric environment, the system becomes bistable in its electronic configuration
at certain number of electrons. At such a condition, the persistent current has a nonzero value
even at the (almost) zero applied Aharonov–Bohm flux, and results in very high magnetic susceptibility
dM/dH at small nonzero fields, followed by an oscillatory dependence at larger fields.
We tentatively assume that previously observed oscillatory magnetization in cyclic metallo-organic
molecules by Gatteschi et al. can be attributed to persistent currents. If this proves correct,
it may open an opportunity (and, more generally, macromolecular cyclic structures may suggest
the possibility) of engineering quantum computational tools based on the Aharonov–Bohm effect
in ballistic nanostructures and macromolecular cyclic aggregates.